By PETER URBEN, Leslie Bretherick
Experiences of past versions: 'an impressive text...thoroughly advised' Loss Prevention Bulletin 'a publication that are meant to be in each laboratory, chemical plant, emergency reaction and fireplace keep watch over heart, university and faculty ... I commend this e-book to an individual enthusiastic about chemical security and hygiene' Chemical and Engineering information '..a ebook that each chemist must have on their shelf' New Scientist 'This ebook is still a vital resource of reference for all these approximately to embark upon unknown brews and concoctions of likely blameless chemical substances' Chemistry and Industry'The indexes are first-class, and there are very beneficial cross-references among assorted species and diverse reactions.' selection 'It can be a really invaluable and quickly access into the literature at the many risky chemical substances which have been synthesized and characterised in the course of the twentieth century.' selection 'Bretherick' is generally authorized because the reference paintings on reactive chemical risks and is vital for all these operating with chemical substances. It comprises each chemical for which documented details on reactive risks has been chanced on. The textual content covers over 5000 parts and compounds and as many back of secondary entries regarding or extra compounds. one in all its most precious positive aspects is the broad pass referencing all through either sections which hyperlinks related compounds or incidents no longer evidently comparable. The 6th version has been thoroughly up to date and revised through Peter Urben and comprises documented details on dangers and acceptable references as much as 1999 quantity 1 is dedicated to precise info at the balance of the indexed compounds, or the reactivity of combos of 2 or extra of them lower than numerous conditions. every one compound is pointed out through an UPAC-based identify, the CAS registry quantity, its empirical formulation and constitution. each one description of an incident or violent response provides connection with the unique literature. each one chemical is assessed at the foundation of similarities in constitution or reactivity, and those teams are indexed alphabetically in quantity 2. the gang entries include a whole directory of all of the compounds in quantity 1 assigned to that crew to help move referral to related compounds. quantity 2 additionally comprises risk subject entries prepared alphabetically, a few with lists. Appendices contain a fireplace similar info desk for larger danger chemical compounds, indexes of registry numbers and chemical names in addition to reference abbreviations and a thesaurus.
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Extra resources for Bretherick's Handbook of Reactive Chemical Hazards, Sixth Edition
Aluminium-dusty overalls were cleaned by immersion in trichloroethylene. During subsequent drying, violent ignition occurred. This was attributed to presence of free hydrogen chloride in the solvent, which reacted to produce aluminium chloride . This is known to catalyse polymerisation of trichloroethylene, producing more hydrogen chloride and heat. The reaction is self-accelerating and can develop a temperature of 1350° C . Trichloroethylene cleaning baths must be kept neutral with sodium carbonate, and free of aluminium dust.
Eng. News, 1954, 32, 1824 10. , 1973 11. , Ind. Acc. Prev. Bull. RoSPA, 1953, 21, 60 12. Wendon, G. , 1973 13. Coffee, R. , 1971, 5, 113 14. Schwab, R. , 113 15. , 114 16. Heinrich, H. , Arbeitsschutz, 1966, 156–157 17. Lamoroux, A. , M´em. Poudres, 1957, 39, 435–445 18. Hamstead, A. C. , Corrosion, 1958, 14, 189t–190t 19. , Ind. Eng. , 1948, 40, 756 20. MCA Case History No. 2160 21. , Ind. Eng. , Prod. Res. , 1976, 15, 150 22. Wendon, G. , Ind. Eng. , Prod. Res. , 1977, 16, 112 23. , Ind. Eng.
See Silver nitride See other METAL HALIDES, SILVER COMPOUNDS 0009. Silver azide chloride [67880-13-1] AgClN3 N3 AgCl Frierson, W. J. , J. Amer. Chem. , 1943, 65, 1698 It is shock sensitive when dry. See other METAL AZIDE HALIDES, SILVER COMPOUNDS 0010. Silver chlorite [7783-91-7] AgClO2 AgOClO Alone, or Iodoalkanes Levi, G. , Gazz. Chim. Ital. , 1923, 53, 40 The salt is impact-sensitive, cannot be finely ground, and explodes at 105° C. Attempts to react silver chlorite with iodo-methane or -ethane caused explosions, immediate in the absence of solvents, or delayed in their presence.
Bretherick's Handbook of Reactive Chemical Hazards, Sixth Edition by PETER URBEN, Leslie Bretherick